Controlled multi-vinyl monomer homopolymerization through vinyl oligomer combination as a universal approach to hyperbranched architectures

Water soluble hyperbranched polymers from controlled radical homopolymerization of PEG diacrylate

A series of water soluble PEG based hyperbranched polymers were successfully synthesized by homopolymerization of poly(ethylene glycol) diacrylate (PEGDA) (Mn 1⁄4 575 and 700 g mol 1 respectively) via vinyl oligomer combination. The homopolymerization of diacrylate macromers underwent a slow vinyl propagation combined with a polycondensation by coupling of reactive oligomers. At a high initiato...

Results of sputum, cytology among workers exposed to vinyl chloride monomer and to poly(vinyl chloride).

The results of systematic cytological sputum examinations of 3,380 Italian VC-PVC industry workers and of 2,287 workers in other industries at different potential risk and chosen as control groups are reported. The results indicate an increase in cellular abnormalities and dysplasias in the epithelium of the respiratory tract among VC-PVC workers. These data are in line with experimental result...

Single cyclized molecule structures from RAFT homopolymerization of multi-vinyl monomers.

We explore a kinetically controlled strategy to suppress the gelation in the homopolymerization of multi-vinyl monomers (MVMs) via RAFT polymerization. We report the generation of 3D single cyclized polymer structures from the RAFT process, which significantly contradicts the classic F-S theory. This approach enables synthesis of a new generation of nanosize macromolecular architectures.

Single cyclized molecule structures from RAFT homopolymerization of multi-vinyl monomersw

Biochemical and Histopathological Effects of Acute Exposure to Vinyl Acetate Monomer Vapour in Wistar Rats

Background: Vinyl acetate monomer is a commodity chemical widely used in the manufacturing of various products. The chemical is hazardous and exposure to it may occur in both occupational and non-occupational settings. The aim of this study was to characterize the effects of short-term exposure to Vinyl Acetate Monomer (VAM) vapour on the liver and lungs of Wistar rats. Methods: Mice weighing ...